The country star, a three-time CMA winner, hasn’t performed on the awards telecast since 2006.
Hill joins a star-studded lineup that includes all five entertainer of the year nominees _ Taylor Swift, Jason Aldean, Brad Paisley, Blake Shelton and Keith Urban.
Other performers include Lady Antebellum, Miranda Lambert and The Band Perry.
Paisley, the reigning entertainer of the year, will host the awards with Carrie Underwood.
The show airs Nov. 9 on ABC from Nashville.